Hardy debuted in Total Nonstop Action Wrestling (TNA) on June 23, 2004, at the Second Anniversary Show , in a match against . Styles , for the TNA X Division Championship .  He also debuted his new entrance theme "Modest", a song performed by Hardy himself, and a new nickname, "The Charismatic Enigma".  The match ended in a no contest when Kid Kash and Dallas interfered.  Hardy returned to TNA on July 21 and was awarded a shot at the NWA World Heavyweight Championship .  Hardy challenged for the title on September 8, losing to NWA World Heavyweight Champion Jeff Jarrett .  In October 2004, he won a tournament,  earning a shot at the NWA World Heavyweight Championship on November 7 at Victory Road , TNA's first monthly pay-per-view.  Hardy was defeated by Jarrett once again in a ladder match at Victory Road following interference from Kevin Nash and Scott Hall . 
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The Nitrox Pump is made up of several ingredients that have been selected as they have been associated with increased production of nitric oxide in the muscles. Nitric oxide synthases (NOS) are enzymes that convert Arginine and citrulline to nitric oxide. Nitric oxide is a key biological messenger, playing a role in a variety of biological processes. It is known as a vasodilator which enhances blood flow in the body which could in theory increase the delivery of oxygen and nutrients to exercising muscle. This is associated with enhanced muscle pumps during exercise. A low level of nitric oxide is associated with physical fatigue.